Fenton-type chemistry by a copper enzyme: molecular mechanism of polysaccharide oxidative cleavage
B. Bissaro, A. K. Rohr, M. Skaugen, Z. Forsberg, S. J. Horn, G. Vaaje-Kolstad, V. Eijsink
This study identifies H2O2 as the co-substrate for LPMOs, revealing a mechanism for polysaccharide oxidative cleavage and improving enzymatic stability and activity.
bioRxiv · Dec 27, 2016Biochemistry